Fluorescence sensing of spermine with a frustrated amphiphile.

نویسندگان

  • Ziya Köstereli
  • Kay Severin
چکیده

A charge-frustrated amphiphile composed of a pyrene-1,3,6-trisulfonate head group and an eicosane side chain can be used as a fluorescence chemosensor for spermine. The sensor allows the detection of spermine down to the nanomolar concentration range with good selectivity over closely related biogenic amines such as spermidine.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A novel diethyl 2-(9-fluorenyl) malonate functionlized SBA-15 for selective optical sensing of Iron

In this study, highly ordered mesoporous silica material (SBA-15) functionalized with Diethyl 2 - (9 -fluorenyl) malonate as a flourophore is reported. The anchoring of flourophores to the hydroxyl group on SBA-15 surface was done with post synthesis method. The obtained materials were characterized by small and wide angle X-ray diffraction, N2 adsorption–desorption, Fourier transform infrared ...

متن کامل

Fluorescence Chemosensing of Mg2+ by Phenylhydrazone of a Difluorenylpiperidin-4-one

Magnesium is an abundant element in the environment. Magnesium ion sensing by fluorescence spectral method is of importance due to the need for the detection of the metal in the human body and the environment. In this paper, we report the Mg2+ ion sensing behavior of the phenylhydrazone derivative of a difluorenylpiperidin-4-one. The preparation method of this compound is simple. The compound s...

متن کامل

A Novel pH-Sensitive Chiral Amphiphile: Synthesis, Aggregation, and Interaction with â-Cyclodextrin

A novel pH-sensitive chiral amphiphile, N-(4-decyloxy-2hydroxybenzylidene)-L-leucine, was synthesized. Two kinds of vesicles were found at different pH ranges, 6.5-8.0 and 11.5-12.5, and a helical structure was observed at pH ) 11.0. This unique behavior can be attributed to the formation of a dimeric structure. The interaction between this amphiphile and â-cyclodextrin was investigated by fluo...

متن کامل

Binding of aromatic anion amphiphile to phospholipid vesicles: a fluorescence study

The fluorescence properties of an aromatic anion amphiphile, N-(4-decyloxy-2-hydroxy-benzylidene)glycine (C10HG) have been investigated. The fluorescence spectra of C10HG in lipid vesicles showed stronger intensity than that in aqueous solution, which is due to the less polarity of microenvironment in the former case. A blue-shift maximum of C10HG fluorescence spectra caused by the carbonyl and...

متن کامل

Nanobiosensors and fluorescence based biosensors: An overview

A biosensor can sense biological elements after interaction with the recognition element. The signal produced due to interaction of the analyte with its biochemical element is transduced by a transducer and detected by appropriate modes. The miniaturization of these biosensors at the nano level using nanostructures as a platform for sensing the analyte or its detection is called a nanobiosensor...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 48 47  شماره 

صفحات  -

تاریخ انتشار 2012